Balanced water purification composition

ABSTRACT

A balanced water purification composition is provided with a buffer compound, and oxidizer/clarifier compound, and a biocide compound. The composition purifies and clarifies water while maintaining the existing water pH. The composition may also include a filtration aid, an algicide, a calcium releasing source, a chelator, and a sequestering agent.

TECHNICAL FIELD

The present invention relates generally to chemical compositions used inthe purification, clarification, and stabilization of water and wastewater, methods for making the compositions, and methods for using thecompositions. More specifically, the present invention relates tochemical compositions, methods for making the compositions, and methodsfor using the compositions in the purification, clarification, andstabilization of recreational waters such as swimming pool, spa, orhot-tub water.

BACKGROUND

The provision of safe and clean water is important in municipal,industrial, and recreational applications. Conventional water treatmentsemploy physical, chemical, and biological processes either alone or incombination to produce a product water of acceptable quality.

In applications where water is intended for human contact orconsumption, the water must be treated so that it is aestheticallypleasing in terms of taste, color, turbidity, odor, and pH,environmentally safe, and effectively free of pathogens and chemicalsresponsible for both acute and chronic illness. Conventional methods usechemicals as oxidizers, biocides, algicides, and pH buffers for thetreatment of water and waste water. Typically, the chemicals are addedto the water separately as part of an overall water maintenance orpurification program. The water is monitored on an hourly, daily, orweekly basis, and when a particular treatment parameter is notacceptable or in compliance with regulatory levels, the appropriateamount of the necessary chemical is added. Often, treatment of one waterquality parameter causes another water quality parameter to change.Conventional treatment, therefore, employs a continuous balancingprocess of monitoring water quality parameters and dosing with variouschemicals to create and to maintain the appropriate water quality.

Combinations of two or more chemicals attempt to improve the ease andreliability of chemical treatments for clarifying or disinfecting water.For example, U.S. Pat. No. 5,501,802 to Thorpe et al. discloses acomposition containing a polyhexamethylene biguanide sanitizer,persulfate salt oxidizers, and chelating agents. The composition is usedto achieve water clarity. U.S. Pat. Nos. 5,514,287 and 5,478,482, bothto Jones et al., disclose a composition and a method for controllingmicrobial growth in recirculating water systems. The compositionincludes a soluble boron contributor, a halogen/boronsanitizer/algicide, and an oxidizing clarifier having a chlorinecompound, a non-halogen oxidizer, and a boron source. Finally, U.S. Pat.No. 4,846,979 to Hamilton discloses an algicide composition for treatingswimming pools and spas including and alkali metal, alkaline earth metalor ammonium bromide and an oxidizer. The composition is metered in overtime to maintain a desired bromine concentration. These chemicalcombinations are not complete water quality treatments. Further, theaddition of these chemicals causes other water quality parameters tochange, such as pH, requiring additional chemical treatment tocompensate for the addition of these chemicals.

In other applications, for example swimming pools and spas, chemicalcombinations attempt to provide a complete water quality treatment. Forexample, U.S. Pat. No. 5,700,877 to Cox discloses a complete treatmentfor the purification of water in non-porous swimming pools, obviatingthe need for the addition of any other compounds to the water. Thecomplete treatment chemical composition of Cox includes a peroxidecompound, an ammonium-based biocidal compound, an acidic compound, abasic compound, a calcium-releasing basic compound, and EDTA. Thecomposition is added to the water when the pH of that water is outsidethe human comfort zone of 7.2 to 7.6 in order to bring the pH within thezone range. Therefore, water clarification is combined with pHadjustment.

The need exists for a composition that acts as a biocide, oxidizer,clarifier, and algicide and does not interfere with the overallmaintenance of the water. Since water conditions vary from applicationto application, the composition of the present invention is formulatedto provide purification and clarification without adversely affectingconcurrent treatment. Benefits include ease of operation for a consumerin pool or spa applications, decreased costs to industry in terms ofchemicals and training and time in an industrial process or wasteapplication, and decreased costs to municipal water supplies withlimited budgets, space, and equipment. The present composition andtreatment method is useful in a variety of applications including homewater treatment, community water treatment, industrial water treatment(both waste water and process water), agriculture, water reuse,groundwater injection, and recreational water applications.

SUMMARY OF THE INVENTION

In accordance with the present invention, applicants have discoveredcompositions and a method for making the compositions to purify waterwhile maintaining the desired water balance upon the addition of thecomposition to water.

When added to water independently maintained at a predetermined pH andhaving a certain temperature range, the compositions do not change thepH of the water. The compositions include a buffer compound having anacidic component and a basic component, the acidic and basic componentsbeing present in amounts such that the molar ratio of the acidiccomponent to the basic component yields a buffer compound whose pH insolution corresponds to the predetermined pH of the water to bepurified, a biocide compound present in an amount sufficient toinactivate the microorganisms in the water to be purified, and anoxidizer/clarifier compound present in an amount sufficient to oxidizethe biocide precursor completely. The acidic component includes, but isnot limited to, sodium bisulfate. The basic component includes, but isnot limited to, sodium bicarbonate and sodium carbonate.

In one formulation of the compositions, the acidic component is sodiumbisulfate, the basic component is sodium bicarbonate and the molar ratioof sodium bisulfate to sodium bicarbonate is about 0.26 to about 0.14,corresponding to a buffer compound pH in solution from about 6.8 up toabout 7.2. In another formulation, the acidic component is sodiumbisulfate, the basic component is sodium bicarbonate, and the molarratio of sodium bisulfate to sodium bicarbonate is about 0.18,corresponding to a buffer compound pH in solution of about 7.

In terms of weight percents, the acidic component can be present in thecompositions from about 1.6 up to about 21 weight percent and the basiccomponent is present in the composition from about 3 up to about 28weight percent. This is true, for example, when the acidic component issodium bisulfate, the basic component is sodium bicarbonate and theweight ratio of sodium bisulfate to sodium bicarbonate is about 0.27.Alternatively, the acidic component is present in the composition fromabout 6 up to about 20.6 weight percent and the basic component ispresent in the composition from about 4.5 up to about 15.4 weightpercent. In this case, the acidic component is sodium bisulfate, thebasic component is sodium carbonate and the weight ratio of sodiumbisulfate to sodium carbonate is about 1.34.

In other formulations, the weight ratio of the acidic component to thebasic component compensates for an increase in the pH of the water overtime associated with water systems exposed to the atmosphere. Forexample, the acidic component can be sodium bisulfate, the basiccomponent sodium bicarbonate, and the weight ratio of sodium bisulfateto sodium bicarbonate about 1.5 to yield a buffer pH of about 4.Alternatively, the acidic component can be sodium bisulfate, the basiccomponent sodium carbonate, and the weight ratio of sodium bisulfate tosodium carbonate about 2.27.

The biocide compound can be Cl₂, Br₂, I₂, alkali metal hypochlorite,alkaline earth metal hypochlorite, chlorinated isocyanurates, PHMB(poly(hexamethylene biguanide) hydrochloride), or halogenatedhydantoins. Preferably, the biocide compound is a halide salt ofammonium or sodium, specifically ammonium chloride, ammonium bromide, orsodium bromide. The biocide compound can be present in the compositionin an amount from about 18 up to about 35 weight percent.

The oxidizer/clarifier compound includes a peroxide, potassiummonopersulfate, alkali metal perborate, or alkali metal persulfate.Preferably, the oxidizer/clarifier compound is sodium persulfate orpotassium persulfate. The oxidizer/clarifier compound can be present inthe composition in an amount from about 38 up to about 64 weightpercent. In one formulation, the oxidizer/clarifier compound is presentin an amount sufficient to oxidize the biocide compound completely andto oxidize organic contaminants in the water to be purified. In thiscase, the molar ratio of the oxidizer/clarifier compound to the biocideprecursor is greater than about 1.

In terms of concentration in the water, the oxidizer/clarifier compoundis present in the composition in an amount such that when thecomposition is added to water the concentration of theoxidizer/clarifier compound in the water is from about 2 up to about 9parts per million. Preferably, the concentration of theoxidizer/clarifier in the water is about 5 ppm.

In one formulation, the biocide precursor is ammonium chloride and ispresent in the composition from about 18 up to about 23 weight percent.The oxidizer/clarifier compound is sodium persulfate and is present inthe composition from about 50 up to 64 weight percent, and the weightratio of sodium persulfate to ammonium chloride is about 2.8. In anotherformulation, the biocide compound is sodium bromide and is present fromabout 25 up to about 35 weight percent. The oxidizer/clarifier compoundis sodium persulfate and is present from about 38 up to about 52 weightpercent, and the weight ratio of sodium persulfate to sodium bromide isabout 1.48.

The balanced water purification composition may include additionalcompounds including an algicide. The algicide includes copper sulphate,copper citrate, copper EDTA (ethylene diaminetetraacetic acid), coppergluconate, silver nitrate, colloidal silver, silver metal deposit onaluminum, quaternary (quats) or polyquaternary (polyquats) ammoniumcompounds (e.g. poly[oxyethylene (dimethylimino) ethylene(dimethylimino) ethylene dichloride]), sodium dimethyldithiocarbamate,2-chloro-4,6-bis(ethylamino)-5-triazine, zinc chloride, or zinc oxides.In one formulation, the algicide is copper sulphate and is present fromabout 1 up to about 2 weight percent. In another formulation, thealgicide is copper citrate and is present from about 1.5 up to about 2weight percent. The copper citrate can be formed in-situ by combiningcopper sulphate and sodium citrate in the composition in about a 1 to 1molar ratio.

The balanced water purification composition may also include one or moreof a chelating agent such as EDTA acid present from about 4.5 up toabout 14.5 weight percent, phosphates, organic phosphonates,polyphosphonates, alkali metal EDTA, EDTA salts such as di-sodium EDTA,or citric acid, a filtration aid such as aluminum sulphate from about 1up to about 4 weight percent, a calcium releasing compound, a scaleinhibitor, and a sequestering agent.

In one formulation of the balanced water purification composition, theacidic component is sodium bisulfate and is present in an amount fromabout 1.6 to about 6.1 weight percent. The basic component is sodiumbicarbonate present in an amount from about 5.9 to about 22.4 weightpercent. The weight ratio of sodium bisulfate to sodium bicarbonate isabout 0.27. The biocide compound is ammonium chloride and is present inan amount from about 18 up to about 23 weight percent. Theoxidizer/clarifier compound is sodium persulfate present in an amountfrom about 50 to about 64 weight percent, and the weight ratio of sodiumpersulfate to ammonium chloride is about 2.8. This formulation may alsoinclude copper sulphate in an amount from about 1 up to about 2 weightpercent.

In another formulation of the balanced water purification composition,the acidic component is sodium bisulfate and is present in an amountfrom about 2.7 up to about 7.6 weight percent. The basic component issodium bicarbonate and is present in an amount from about 10 up to about28 weight percent. The weight ratio of sodium bisulfate to sodiumbicarbonate is about 0.27. The biocide compound is sodium bromidepresent in amount from about 25 up to about 35 weight percent. Theoxidizer/clarifier compound is sodium persulfate present in an amountfrom about 38 up to about 52 weight percent, and the weight ratio ofsodium persulfate to sodium bromide is about 1.48. This formulation mayalso include copper sulfate present from about 1 up to about 2 weightpercent or copper citrate from about 1 up to about 2 weight percent.

The balanced water purification composition includes a a water solublefilm bag for holding a predetermined amount of the compositions. Thewater soluble film bag includes polyvinyl alcohol (PVOH), a cellulosicpolymer, or polyethylene oxide.

The method for making the balanced water purification composition to beused in conjunction with existing water treatment without affecting thepH of the water includes determining the pH and temperature range of thewater to be treated, formulating a buffer compound having an acidiccomponent and a basic component present in a molar ratio correspondingto the pH of the water to be treated, adding a sufficient amount of abiocide compound to inactivate the biological contaminants in the water,and adding a sufficient amount of a clarifier/oxidizer compound tooxidize the biocide precursor completely and to oxidize organiccontaminants in the water. This method of making also includes adding apredetermined amount of the composition to a water soluble film orlaminated film bag, where the water soluble film bag includes polyvinylalcohol, a cellulosic fiber, polyethylene oxide, or laminates thereof.The balanced water purification composition can be used in purifying andclarifying recreational waters.

DETAILED DESCRIPTION OF THE INVENTION

The composition of the present invention includes an oxidizer/clarifiercompound, a biocide compound, and a buffer compound. The buffer compoundincludes an acidic component and a basic component. The composition istypically made from inorganic salts. Generally, these salts dissociateupon addition to water, affecting water balance including pH, totalalkalinity, and hardness. The composition of the present invention,however, is formulated to provide water clarification and purificationin conjunction with an existing overall water maintenance programwithout adversely affecting other water quality parameters. Therefore,given a predetermined water pH and water temperature range, the molarratios of the compounds and components of the composition of the presentinvention are calculated from their dissociation constants to yield a pHin solution equivalent to the predetermined pH of the water to betreated. The calculated molar ratios are used to determine the weightpercent ratios of the components (i.e. molar ratios of dissociatedspecies determine the weight ratios of compounds and the components).Therefore, water balance is maintained when the composition soformulated is added to the water.

The buffer compound is formulated to have a pH in solution correspondingto the pH of the water to be treated. Therefore, the type and weightpercent of the acidic component and the basic component of the buffercompound are selected to provide the desired pH at the appropriate watertemperature. The basic component includes, but is not limited to, sodiumbicarbonate and sodium carbonate. The acidic component includes, but isnot limited to sodium bisulfate. Typically, the buffer compound includessodium bisulfate and at least one of sodium bicarbonate and sodiumcarbonate. The buffer compound may also include phosphates such asmonopotassium phosphate, monobasic sodium phosphates, andcitrate-phosphate blends.

In order to achieve the desired buffer solution pH, the molar ratio ofthe acidic component to the basic component is calculated. Calculationof the molar ratio is governed by the following reactions describing thecarbonate system and showing the generation of bicarbonate and carbonateions respectively: ##STR1## where k₁ and k₂ are the dissociationconstants. Given a desired pH of the water at a given temperature, themolar ratios can be determined. By way of illustration, using a sodiumbicarbonate basic component at a pH of about 7 and a water temperatureof about 25° C., the dissociation constants are k₁ =4.45×10⁻⁷, and k₂=4.7×10⁻¹¹. Solving the equation:

    pH=pKa.sub.1 +log ([HCO.sub.3.sup.- ]/[H.sub.2 CO.sub.3 ])

yields a molar ratio after equilibrium of the basic form (HCO₃ ⁻) to theacidic form (H₂ CO₃) of 4.45. To convert the basic form to the acidicform, an appropriate amount of a proton donor, for example, sodiumbisulfate (NaHSO₄), is combined with sodium bicarbonate. The formationof 1 equivalent of the acidic form will require 1 equivalent of sodiumbisulfate. Given the molar ratio at equilibrium of the basic and acidicforms, the initial molar ratio of the combination of sodium bisulfate tosodium bicarbonate for generation of the amount of the acidic formrequired at pH 7 is about 0.18.

In general, for a buffer compound utilizing sodium bisulfate, sodiumbicarbonate, or sodium carbonate in water having a temperature fromabout 20° C. up to about 30° C. and a pH from a pH of about 4 up to a pHof about 10 the following molar ratios apply. For a pH of 4, the initialmolar ratio of sodium bisulfate to sodium bicarbonate is about 1. Atthis pH, no sodium carbonate is required. As the pH increases to about8.3, this molar ratio decreases until only sodium bicarbonate isrequired at a pH of about 8.3. Above a pH of 8.3, sodium carbonate isrequired in addition to sodium bicarbonate. As the pH increases fromabout 8.3 up to about 10, the initial ratio of sodium carbonate tosodium bicarbonate increases up to about 0.47. In one embodiment, thebuffer compound includes sodium bisulfate as the acidic component,sodium bicarbonate as the basic component, a water temperature rangefrom about 20° C. up to about 30° C., and an initial molar ratio ofsodium bisulfate to sodium bicarbonate from about 0.26 for a pH of about6.8 to a molar ratio of about 0.14 for a pH of about 7.2.

After the acidic and basic components are selected and their molarratios are calculated based upon pH and temperature, the initial molarratios are converted to weight percent ratios based upon the molecularweights of the components. In one embodiment, the acidic component issodium bisulfate, the basic component is sodium bicarbonate, and theweight ratio of sodium bisulfate to sodium bicarbonate is about 0.27,corresponding to a pH of about 7. This embodiment is useful forrecreational water applications such as swimming pool water. In anotherembodiment, the acidic component is sodium bisulfate, the basiccomponent is sodium carbonate, and the weight percent ratio of thesodium bisulfate to the sodium carbonate is about 1.34, alsocorresponding to a pH of about 7. Although the buffer compound in thepreceding embodiments has enough buffering capacity to assist inmaintaining the pH of the water over time and to account for changes inthe pH of the water due to the addition of other chemicals, the pH in awater system that is open to the atmosphere will tend to increase overtime. Therefore, an acidic variant of the buffer compound can bespecifically formulated to compensate for this increase. In oneembodiment of the acidic variant, the cidic component is sodiumbisulfate, the basic component is sodium bicarbonate, and the weightratio of sodium bisulfate to sodium bicarbonate is about 1.5,corresponding to a pH of about 4. In another embodiment of the acidicvariant, the acidic component is sodium bisulfate, the basic componentis sodium bicarbonate, and the weight ratio of sodium bisulfate tosodium bicarbonate is about 3.1, corresponding to a pH of about 2.78. Inyet another embodiment of the acidic variant, the acidic component issodium bisulfate, the basic component is sodium carbonate and the weightratio of sodium bisulfate to sodium carbonate is 2.27, corresponding toa pH of about 4. Similarly, the buffer compound can be formulated as abasic variant. In one embodiment of the basic variant, the acidiccomponent is sodium bisulfate, the basic component is sodium carbonateand the weight ratio of sodium bisulfate to sodium carbonate is about0.77, corresponding to a pH of about 10.

Finally, the weight percents for each component in the buffer compoundare expressed in ranges based upon the possible maximum and minimumamounts of the other compounds in the composition. In one embodiment,the acidic component is sodium bisulfate, the basic component is sodiumbicarbonate, the sodium bisulfate is present from about 1.6 up to about21 weight percent, and the sodium bicarbonate is present from about 3 upto about 28 weight percent. In another embodiment, the acidic componentis sodium bisulfate, the basic component is sodium carbonate, the sodiumbisulfate is present form about 6.0 up to about 20.6 weight percent, andthe sodium carbonate is present from about 4.5 up to about 15.4 weightpercent.

The biocide compound is selected to provide chemical inactivation of thebiological or microbiological contaminants in the water. The biocidecompound includes Cl₂ (gas), Br₂, I₂, alkali metal and alkaline earthmetal ypochlorite (e.g. LiOCl, NaOCl, and Ca(OCl)₂), chlorinatedisocyanurates, PHMB(poly(hexamethylene iguanide)hydrochloride), orhalogenated hydantoins. In a referred embodiment the biocide compound isadded as a halide salt of ammonium or sodium. In a more preferredembodiment, the biocide compound is ammonium chloride. In a mostpreferred embodiment, the biocide compound is sodium bromide or ammoniumbromide. Bromide is preferred over chloride because of health concernsover chlorinated by-products, and because bromine is not as pH sensitiveas chlorine, bromine causes less eye irritation. Odor formation isreduced when using bromide, and bromamines have a much greater biocidalefficiency than chloramines.

The biocide compound is present in an amount necessary to inactivate thebiological contaminants, including bacteria, viruses, and protozoa, andto maintain a biocide residual in the water necessary to meet regulatoryrequirements, to prevent regrowth of the biological contaminants, or toinactivate biological contaminants subsequently introduced into thewater. The biocide compound is present in the composition in an amountfrom about 18 up to about 35 weight percent. In one embodiment, thebiocide compound is ammonium chloride and is present in the compositionin an amount from about 18 up to about 23 weight percent. Althoughammonium chloride is a weak acid salt, the conjugate base is notpresent. Therefore, ammonium chloride does not act as a buffer nor doesit affect the buffer pH. In a preferred embodiment, the biocide compoundis sodium bromide and is present in the composition from about 25 up toabout 35 weight percent.

The oxidizer/clarifier compound is added to oxidize organic matter inthe water and to oxidize the biocide compound, for example oxidizingchloride to chlorine and bromide to bromine. The oxidizer/clarifiercompound includes peroxides, hydrogen peroxide, potassiummonopersulfate, and alkali metal perborate. In a preferred embodiment,the oxidizer/clarifier compound is an alkali metal persulfate. In a morepreferred embodiment, the alkali metal persulfate is sodium persulfateor potassium persulfate. In a most preferred embodiment, the alkalimetal persulfate is sodium persulfate.

The oxidizer/clarifier compound is present in an amount necessary tooxidize the organic matter present in the water, to oxidize the biocideprecursor compound completely, and to maintain a oxidizer/clarifierresidual in the water necessary to oxidize any organic material that maybe subsequently introduced into the water. In one embodiment, theoxidizer/clarifier compound is present in the composition in an amountfrom about 38 weight percent up to about 64 weight percent. In anotherembodiment, the oxidizer/clarifier compound is present on thecomposition in an amount from about 50 up to about 64 weight percent. Inyet another embodiment, the oxidizer clarifier compound is present inthe composition in an amount from about 38 up to about 52 weightpercent. In a preferred embodiment, the oxidizer/clarifier compound ispresent in the composition in an amount sufficient to achieve aconcentration in the water of the oxidizer/clarifier compound from about2 up to about 9 parts per million (ppm). In a more preferred embodiment,the oxidizer/clarifier compound is present in the composition in anamount sufficient to achieve a concentration in the water of theoxidizer/clarifier compound of about 5 ppm.

In order for the oxidizer/clarifier compound to oxidize the biocidecompound, the amount of the oxidizer/clarifier compound in thecomposition is selected to be more than that of the biocide compound inthe composition. The molar ratio of the oxidizer/clarifier compound tothe biocide compound is formulated to be at least 1 to 1 with any excesspersulfate oxidizing the organic matter present in the water. By way ofexample, assume the conversion of chloride to chlorine by persulfate isgoverned by the reaction:

    S.sub.2 O.sub.8.sup.2- +2Cl.sup.- →2SO.sub.4.sup.2- +Cl.sub.2, E°=0.7 V.

In order to have a sufficient amount of persulfate to oxidize thebiocide and the organic matter, the persulfate to chlorine ratio (S₂ O₈²⁻ /Cl₂) is greater than 1:1 in the water, for example, about 1 to 0.8,is selected, yielding a molar ratio of persulfate to chloride (S₂ O₈ ²⁻/Cl⁻) in the composition of about 1 to 1.6. This yields a weight ratioof sodium persulfate to ammonium chloride in the composition of about2.8. In a preferred embodiment, the oxidizer/clarifier is sodiumpersulfate, the biocide is ammonium chloride, and the weight ratio ofsodium persulfate to ammonium chloride is about 2.8. In a more preferredembodiment, the oxidizer/clarifier is sodium persulfate, the biocide issodium bromide, and the weight ratio of sodium persulfate to sodiumbromide is 1.48.

Although not required in the composition of the present invention toprovide purification, disinfection, and clarification without adverselyaffecting the existing water balance, additional compounds may be addedto the composition of the present invention in response to applicationspecific water quality demands. These additional compounds includealgicides, calcium releasing compounds, chelators, scale inhibitors,sequestering agents, and filtration aids (i.e. coagulants andflocculants).

In applications where algae growth is a concern, an algicide compoundmay be added to control the growth of the algae. This is true, forexample, of applications exposed to the environment. The algicidecompound includes metal complexes such as copper sulphate, coppercitrate, copper EDTA, and copper gluconate, silver nitrate, colloidalsilver, silver metal deposits on aluminum, polyquats such aspoly[oxyethylene (dimethylimino) ethylene (dimethylimino) ethylenedichloride], quats, sodium dimethyldithiocarbamate, and2-chloro-4,6-bis(thylamino)-5-triazine, and zinc compounds such as zincchloride and zinc oxides. In a preferred embodiment, the algicide iscopper sulfate. In a more preferred embodiment, the algicide is coppercitrate. In a most preferred embodiment, the copper citrate is formedin-situ by combining copper sulfate and sodium citrate together in thecomposition in a 1:1 molar ratio. The algicide is present in thecomposition in an amount from about 1 weight percent up to about 2weight percent.

Although calcium maintenance is not required for the application of thepresent invention, calcium chloride can be added to the composition tomaintain water hardness in the range of from about 150 up to about 400ppm. The chelators include EDTA acid, EDTA metal salts such as sodiumsalts (disodium, trisodium, and tetrasodium salts), citric acid, sodiumcitrate, phosphates, organic phosphonates, organic olyphosphonates. Thechelators are present in an amount from about 2.5 up to about 18.5weight percent. In one embodiment, the chelating agent is EDTA acid andis present from about 4.5 to about 14.5 weight percent. In anotherembodiment, the chelating agent is disodium EDTA salt and is resent fromabout 2.5 up to about 18.5 weight percent. In a preferred embodiment,the chelating agent is EDTA acid and is present in an amount of about 11weight percent. The scale inhibitors and sequestering agents includepolyacrylates (polyacrylic acid), polycarboxylate, polymaleic acid,tartaric acid, glycolic acid, and polyglycolic acid. In a preferredembodiment, the scale inhibitors are polyacrylate scale inhibitors. Thescale inhibitors and sequestering compounds are formulated to be presentin the treated water in an amount from about 25 up to about 200 ppm. Thefiltration aids include inorganic coagulants including the salts ofaluminum and ferric ions such as aluminum sulphate, ferric sulphate,lime (CaO), glycolic acid, organic coagulants such as organic polymers(often termed polyelectrolytes) including both natural and synthetic,nonionic, anionic, and cationic polymers. In one embodiment, thefiltration aid is a low molecular weight polyacrylate. In anotherembodiment, the filtration aid is aluminum sulfate and is present in anamount from about 1 to about 4 weight percent.

In order to formulate the composition of the present invention, thedesired water quality for the particular application is determined. Theacidic and basic components are selected, and based upon the pH andtemperature of the water, the molar ratio of the acidic component to thebasic component of the buffer compound is calculated. This molar ratioyields a working weight percent range for the buffer compound to use inthe formulation of the composition. The amount of the selected biocidecompound is calculated based upon the anticipated biocide demand in thewater and any required or desired biocide residual in the water. Next,the molar ratio of the desired oxidizer/clarifier compound to thebiocide compound is calculated to provide a molar excess of theoxidizer/clarifier compound to the biocide compound and to meet theoxidant demand of the organic matter in the water. Based upon this molarratio, the weight percents of oxidizer/clarifier and biocide arecalculated from their molecular weights. The weight ratios of the acidiccomponent, basic component, biocide compound, and oxidizer/clarifiercompound are maximized and minimized within working ranges of efficacyto yield weight percent ranges for each constituent in a particularembodiment of the composition. Finally, additional chemical compoundssuch as algicides, calcium releasing compounds, chelators, scaleinhibitors, sequestering agents, and filtration aids are added to thecomposition based upon the needs of the water in the specificapplication. Once formulated, the composition is packaged to permit easyand reliable addition into the water to be treated. The packagingincludes bulk powders, aqueous solutions, tablets, or packets.

In one embodiment, the composition is packaged in soluble film pouches.Soluble pouches provide ease of use, consistency of dose, minimal hazardto the user, and minimal packaging waste. The soluble pouch is made frompolymers, including polyvinyl alcohol, cellulosic polymers, andpolyethylene oxide. In a preferred embodiment, the soluble pouch is madefrom polyvinyl alcohol. The pouch may contain enough composition to madea slurry or solution for metering into the water or may be sized foraddition directly into the water to be treated. The direct addition sizecontains a sufficient amount of the composition such that all thecompounds are present in the water in the desired concentrations uponaddition of a single packet or multiple packets to the water. The directaddition size is ideal for swimming pool and spa applications.

EXAMPLES

Various formulations of the present composition are possible forrecreational water applications such as swimming pools and spas. Theseapplications typically have a pH of 7.2 to 7.6, total alkalinity of 50to 150 ppm, a hardness of 150 to 400 ppm, and a water temperature of 20to 30° C. The composition is formulated based upon these waterconditions such that the pH of the water will not be affected uponaddition of the composition. Numerous proposed formulations areillustrated in the following examples.

Example

    ______________________________________                                        Component          Weight Percent Range                                       ______________________________________                                        Sodium Persulfate  50-61.3                                                    Ammonium Chloride  18-22                                                      Sodium Bisulfate   2.2-5.5                                                    Sodium Bicarbonate 8-20                                                       EDTA               4.5-14.5                                                   Aluminum Sulphate  1-4                                                        Copper Sulphate    1-2                                                        ______________________________________                                    

The weight ratio of sodium bisulfate to sodium bicarbonate is 0.27, andthe weight ratio of sodium persulfate to ammonium chloride is 2.8. Thepersulfate/chloride, bisulfate/bicarbonate pair ratios are based upon apH of about 7.

Example

    ______________________________________                                        Component          Weight Percent Range                                       ______________________________________                                        Sodium Persulfate  50-63                                                      Ammonium Chloride  18-22.5                                                    Sodium Bisulfate   1.6-5.3                                                    Sodium Bicarbonate 5.9-19.7                                                   Disodium EDTA Salt 5-18.5                                                     Aluminum Sulphate  1.0-4.0                                                    Copper Sulphate    1.0-2.0                                                    ______________________________________                                    

Again, the weight ratio of sodium bisulfate to sodium bicarbonate is0.27, and the weight ratio of sodium persulfate to ammonium chloride is2.8. Disodium EDTA salt is substituted for EDTA acid as the chelatingagent.

Example

    ______________________________________                                        Component          Weight Percent Range                                       ______________________________________                                        Sodium Persulfate  50-63                                                      Ammonium Chloride  18-22.5                                                    Sodium Bisulfate   1.6-6.1                                                    Sodium Bicarbonate 5.9-22.4                                                   Disodium EDTA Salt 2.5-5                                                      Copper Sulphate    1-2                                                        ______________________________________                                    

In this example, aluminum sulfate is not added, and disodium EDTA saltis again substituted as the chelating agent. The sodium bisulfate tosodium bicarbonate and sodium persulfate to ammonium chloride weightratios remain 0.27 and 2.8 respectively.

Example 4

    ______________________________________                                        Component          Weight Percent Range                                       ______________________________________                                        Sodium Persulfate  50-61                                                      Ammonium Chloride  18-22                                                      Sodium Bisulfate   6-15.3                                                     Sodium Bicarbonate 4-10.2                                                     EDTA               4.5-14.5                                                   Aluminum Sulphate  1-4                                                        Copper Sulphate    1-2                                                        ______________________________________                                    

In this example the persulfate/chloride weight ratio is again 2.8;however, the bisulfate/bicarbonate weight ratio is increased to 1.5.This acidic variant of the composition is intended to compensate for awater system that is open to the environment causing the pH to increaseover time. The acidic variant controls a pH rise that is greater thanthe buffering capacity of the variant in Example 1. The acid/basedissociation pairs are formulated based upon a pH of about 4.

Example 5

    ______________________________________                                        Component          Weight Percent Range                                       ______________________________________                                        Sodium Persulfate  50-63                                                      Ammonium Chloride  18-22.5                                                    Sodium Bisulfate   4.5-15                                                     Sodium Bicarbonate 3-10                                                       Disodium EDTA salt 5-18.5                                                     Aluminum Sulfate   1-4                                                        Copper Sulfate     1-2                                                        ______________________________________                                    

Again, the persulfate/chloride weight ratio is 2.8, and thebisulfate/bicarbonate weight ratio is 1.5. Disodium EDTA salt issubstituted for EDTA acid as the chelating agent.

Example 6

    ______________________________________                                        Component          Weight Percent Range                                       ______________________________________                                        Sodium Persulfate  50-63                                                      Ammonium Chloride  18-22.5                                                    Sodium Bisulfate   4.5-17.1                                                   Sodium Bicarbonate 3-11.4                                                     Disodium EDTA salt 2.5-5                                                      Copper Sulfate     1-2                                                        ______________________________________                                    

In this example, aluminum sulfate is not added, and disodium EDTA saltis again substituted as the chelating agent. The persulfate/chloride andbisulfate/bicarbonate weight ratios remain 2.8 and 1.5 respectively.

Example 7

    ______________________________________                                        Component          Weight Percent Range                                       ______________________________________                                        Sodium Persulfate  56-64                                                      Ammonium Chloride  20-23                                                      Sodium Bisulfate   2.4-4.6                                                    Sodium Bicarbonate 9-17                                                       Copper Sulphate    1-2                                                        ______________________________________                                    

The specific weight percents are chosen such that the sodium bisulfateto sodium bicarbonate weight ratio is 0.27, and the weight ratio ofsodium persulfate to ammonium chloride is 2.8. This formulation ispreferred for waters where metals are not problematic and filtrationaids are not required but where algae growth is a concern. The variantof this example is based upon a pH of about 7.

Example 8

    ______________________________________                                        Component          Weight Percent Range                                       ______________________________________                                        Sodium Persulfate  56-64                                                      Ammonium Chloride  20-23                                                      Sodium Bisulfate   6.9-13                                                     Sodium Bicarbonate 4.6-8.6                                                    Copper Sulfate     1-2                                                        ______________________________________                                    

The specific weight percents are chosen such that the sodium bisulfateto sodium bicarbonate weight ratio is 1.5, and the weight ratio ofsodium persulfate to ammonium chloride is 2.8. This is the acidicvariant of Example 7 and is preferred for waters open to the atmospherewhere the pH tends to increase over time. The variant of this example isbased upon a pH of about 4.

Example

    ______________________________________                                        Component          Weight Percent Range                                       ______________________________________                                        Sodium Persulfate  38-52                                                      Sodium Bromide     25-35                                                      Sodium Bisulfate   2.7-7.6                                                    Sodium Bicarbonate 10-28                                                      Copper Sulfate     1-2                                                        ______________________________________                                    

This formulation is similar to the formulation of Example 7, with sodiumbromide replacing ammonium chloride as the biocide. The sodium bisulfateto sodium bicarbonate weight ratio is 0.27, and the sodium persulfate tosodium bromide weight ratio is 1.48. The composition is based upon a pHof about 7.

Example 10

    ______________________________________                                        Component          Weight Percent Range                                       ______________________________________                                        Sodium Persulfate  38-52                                                      Sodium Bromide     25-35                                                      Sodium Bisulfate   7.8-21                                                     Sodium Bicarbonate 5.2-14                                                     Copper Sulfate     1-2                                                        ______________________________________                                    

This formulation is an acidic variant of the formulation of Example 9.The sodium bisulfate to sodium bicarbonate weight ratio becomes 1.5,while the sodium persulfate to sodium bromide weight ratio remains 1.48.Again, the acidic variant is preferred for water systems open to theatmosphere that have a tendency to increase pH over time. Thiscomposition is based upon a pH of about 4.

Example 11

    ______________________________________                                        Component          Weight Percent Range                                       ______________________________________                                        Sodium Persulfate  56-61                                                      Ammonium Chloride  20-22                                                      Sodium Bisulfate   3.3-4.6                                                    Sodium Bicarbonate 12.2-17                                                    Copper Citrate     1.5-2                                                      ______________________________________                                    

In this formulation, the weight ratio of sodium persulfate to ammoniumchloride is 2.8, and the weight ratio of sodium bisulfate to sodiumbicarbonate is 0.27. Copper citrate is substituted for copper sulphateas an algicide. Copper citrate is a preferred algicide because it isless sensitive to pH and total alkalinity than copper sulphate, thechelating effect of citrate prevents Cu²⁺ from precipitating, algaecontrol is comparable to copper sulphate, copper citrate has a greaterpotential for eliminating discoloration, and citrate is biodegradablewhen the pH≦6.1. Copper citrate may be formed in-situ by adding coppersulfate and sodium citrate together in the composition in a 1:1 molarratio. This formulation is based upon a pH of about 7.

Example 12

    ______________________________________                                        Component          Weight Percent Range                                       ______________________________________                                        Sodium Persulfate  38-50                                                      Sodium Bromide     25-32                                                      Sodium Bisulfate   3.5-7.5                                                    Sodium Bicarbonate 13-27.5                                                    Copper Citrate     1.5-2                                                      ______________________________________                                    

The weight ratio of sodium persulfate to sodium bromide is 1.48, and theweight ratio of sodium bisulfate to sodium bicarbonate is 0.27. Coppercitrate is substituted for copper sulphate as an algicide for thereasons indicated above in Example 11. This formulation is based upon apH of about 7.

Example 13

    ______________________________________                                        Component          Weight Percent Range                                       ______________________________________                                        Sodium Persulfate  50-61                                                      Ammonium Chloride  18-22                                                      Sodium Bisulfate   6-14.6                                                     Sodium Carbonate   4.5-11.0                                                   EDTA               4.5-14.5                                                   Aluminum Sulphate  1-4                                                        Copper Sulphate    1-2                                                        ______________________________________                                    

Example 14

    ______________________________________                                        Component          Weight Percent Range                                       ______________________________________                                        Sodium Persulfate  50-64                                                      Ammonium Chloride  18-23                                                      Sodium Bisulfate   6.9-17.8                                                   Sodium Carbonate   5.1-13.2                                                   Copper Sulphate    1-2                                                        ______________________________________                                    

Example 15

    ______________________________________                                        Component          Weight Percent Range                                       ______________________________________                                        Sodium Persulfate  38-52                                                      Sodium Bromide     25-35                                                      Sodium Bisulfate   6.3-20.6                                                   Sodium Carbonate   4.7-15.4                                                   Copper Sulphate    1-2                                                        ______________________________________                                    

In examples 13, 14, and 15, sodium carbonate is substituted for sodiumbicarbonate as the basic component of the buffer compound. The weightratio of sodium bisulfate to sodium carbonate is 1.34 for all threeexamples. The weight ratio of sodium persulfate to ammonium chloride is2.8, and the weight ratio of sodium persulfate to sodium bromide is1.48. These three examples are based upon a pH of about 7.

In the following examples, the pH effect on water of variousformulations of the balanced water purification composition was comparedto BAQUACIL™, commercially available from Zenneca, Ltd., andcommercially available water purifications compounds such asCHLOR-FREE™, commercially available from Aqua-Pure International.

Example 16

In this example unbuffered tap water having a pH 7.21, temperature of22.9° C., and total alkalinity of 60 ppm was used in an open system. Thetotal hardness of the water was adjusted to 208 ppm by adding CaCl₂,[Cl₂ ]<0.5 ppm.

The three samples of the balanced water purification composition were:

Sample 1: 57.4% Na₂ S₂ O₈, 20.5% NH₄ Cl, 4.7% NaHSO₄, 17.4% NaHCO₃,where the weight ratio of NaHSO₄ /NaHCO₃ was 0.27.

Sample 2: 58% Na₂ S₂ O₈, 20.70% NH₄ Cl, 13.5% NaHSO₄, 7.8% NaHCO₃, wherethe weight ratio of NaHSO₄ /NaHCO₃ was 1.7.

Sample 3: 58.0% Na₂ S₂ O₈, 20.7% NH₄ Cl, 16.1% NaHSO₄, 5.2% NaHCO₃,where the weight ratio of NaHSO₄ /NaHCO₃ was 3.1.

The results are listed in Table 1.

                  TABLE 1                                                         ______________________________________                                        pH Measured In Open System                                                               Day 2 a.m.                                                         Day 1                       T.A.                                              Sample     pH     Temp (°C.)                                                                       (ppm) pH   Temp (°C.)                      ______________________________________                                        Sample 1 (.001%)                                                                         7.21   23.2      60    7.84 22.9                                   Sample 2 (.001%)                                                                         7.21   23.1      60    7.82 23                                     Sample 3 (.001%)                                                                         7.17   23.3      60    7.81 22.7                                   CHLOR-FREE ™                                                                          7.19   23.1      60    7.83 22.9                                   (.001%)                                                                       CHLOR-FREE ™                                                                          7.25   23.1      60    7.87 23                                     (.00037%)                                                                     BAQUACIL ™                                                                            7.38   23.2      50    7.96 22.8                                   (50 ppm)                                                                      Tap Water  7.21   22.9      60    7.87 23                                     ______________________________________                                    

The concentrations are based on a dosage of 500 grams of product to50,000 liters of water. The tap water was equilibrated at roomtemperature prior to use in these pH experiments and was unstirred. Thewater was not equilibrated with respect to dissolved CO₂. The pH wasmeasured on day 1 after addition of the composition and on the next day,day 2. As can be seen in the table, the addition of the balanced waterpurification composition did not have an effect on the initial, or timezero, pH of the water with the exception of the most acidic variant,sample number 3. The other products did change the pH of the tap waterupon addition.

Example 17

In this example equilibrated unbuffered tap water was stirred overnightto release CO₂. After overnight stirring, the pH of the water was 7.78at a temperature of 21.8° C. and a total alkalinity of 60 ppm. Totalhardness was adjusted to 272 ppm by the addition of CaCl₂, [Cl₂ ]<0.5ppm.

The following samples of the balanced water purification compositionwere used.

Sample A: 58.60% Na₂ S₂ O₈, 21% NH₄ Cl, 12.6% NaHSO₄, 7.8% NaHCO₃, wherethe weight ratio of NaHSO₄ to NaHCO₃ was 1.6.

Sample B: 56% Na₂ S₂ O₈, 20% NH₄ Cl, 11.7% NaHSO₄, 7.8% NaHCO₃, 3% Na₃Citrate 1.5% CuSO₄, where the weight ratio of NaHSO₄ to NaHCO₃ was 1.5.

The results are listed in Table 2.

                  TABLE 2                                                         ______________________________________                                        pH Measured In Open System                                                               Day 2 a.m.                                                         Day 1                       T.A.                                              Sample     pH     Temp (°C.)                                                                       (ppm) pH   Temp (°C.)                      ______________________________________                                        Sample A (.001%)                                                                         7.76   23.0      60    7.74 22.6                                   CHLOR-FREE ™                                                                          7.50   23.0      60    7.59 23.2                                   (.001%)                                                                       Sample B (.001%)                                                                         7.66   23.2      60    7.70 23.4                                   Tap Water (.001%)                                                                        7.78   21.8      60    7.76 23.4                                   ______________________________________                                    

Again, the pH was measured after addition of the composition on day 1and the next day, day 2. As the table illustrates, little or no changein the pH is exhibited upon the addition of the balanced waterpurification composition, especially when compared to the CHLOR-FREE™.

Example 18

The stability and higher solubility of the copper citrate algicideversus copper sulfate was demonstrated across varying pH and totalalkalinity. The actual measurements were made at higher concentrationsto amplify the response of the aqueous solutions. The concentrations ofboth the copper citrate and copper sulfate were 0.0025M. The greaterstability of copper citrate with respect to varying total alkalinity isshown in Table 3. The greater stability of copper citrate with respectto varying pH is shown in Table 4.

                  TABLE 3                                                         ______________________________________                                        Variable Total Alkalinity                                                     T.A. (ppm) pH     Temp (°C.)                                                                         CuSO.sub.4                                                                          Cu Citrate                                ______________________________________                                        700        7.73   23.8        cloudy                                                                              clear                                     450        7.71   23.8        cloudy                                                                              clear                                     280        7.81   24.0        cloudy                                                                              clear                                     150        7.61   23.6        cloudy                                                                              clear                                     80         7.75   23.9        cloudy                                                                              clear                                     ______________________________________                                    

                  TABLE 4                                                         ______________________________________                                        Variable pH                                                                   pH      Temp (°C.)                                                                            CuSO.sub.4                                                                            Cu Citrate                                     ______________________________________                                        4       23.8           clear   clear                                          7       23.8           clear   clear                                          10      24.0           cloudy  clear                                          ______________________________________                                    

A formulation of the balanced water purification composition containingcopper citrate as the algicide was also compared to CHLOR-FREE™ forstability. The results are listed in Table 5.

                  TABLE 5                                                         ______________________________________                                        Comparison to CHLOR-FREE ™                                                 T.A.                              Formulation                                 (ppm) pH     Temp (°C.)                                                                       CHLOR-FREE ™                                                                          containing CuCitrate                        ______________________________________                                        600   7.62   23.9      cloudy     clear                                       350   7.54   24.6      cloudy     clear                                       220   7.64   24.4      slightly cloudy                                                                          clear                                       110   7.59   24.1      clear      clear                                       65    7.59   24.0      clear      clear                                       ______________________________________                                         1)Formulation containing copper citrate: 56% Na.sub.2 S.sub.2 O.sub.8, 20     NH.sub.4 Cl, 11.7% NaHSO.sub.4, 7.8% NaHCO.sub.3, 3% Sodium Citrate, and      1.5% CuSO.sub.4                                                               2)Concentration of the CHLORFREE ™ Commercial product and the              formulation containing copper citrate products are 2 mg/mL (200 times         concentrated than the dosage used in regular swimming pools).            

The concentrated copper citrate solution (0.0025M) and the formulationof the balanced water purification composition containing copper citratehave a wide range of tolerance toward pH (4-10) and total alkalinity(0-700 ppm), whereas the copper sulfate solution (0.0025M) and theCHLOR-FREE™ commercial product containing copper sulfate are more pH andalkalinity sensitive and precipitate out at high pH or high alkalinitydepending on the copper concentration.

The foregoing examples are meant as an illustration of the balancedwater purification composition only and not as a limitation. Those ofordinary skill in the art of water treatment will readily recognize thatmany variations of the balanced water purification composition arepossible and are likely to be an effective water treatment composition.

What is claimed is:
 1. A balanced water purification composition foraddition to and purification of water, which composition does not changethe pH of the water to which it is added, the composition comprising:a)a buffer compound comprising:i) an acidic component; and, ii) a basiccomponent, where the acidic and basic components are present in amountssuch that the molar ratio of the acidic component to the basic componentyields a buffer compound having a pH in solution equivalent to theexisting pH of the water to be purified; b) a biocide compound presentin an amount sufficient to inactivate biological contaminants in thewater to be purified; and c) an oxidizer/clarifier compound present inan amount sufficient to oxidize the biocide compound completely.
 2. Thebalanced water purification composition of claim 1 wherein said acidiccomponent is sodium bisulfate.
 3. The balanced water purificationcomposition of claim 1, wherein said basic component is sodiumbicarbonate or sodium carbonate.
 4. The balanced water purificationcomposition of claim 1 wherein said acidic component is sodiumbisulfate, said basic component is sodium bicarbonate and the molarratio of sodium bisulfate to sodium bicarbonate is about 0.26, when saidbuffer compound pH in solution is about 6.8, to about 0.14, when saidbuffer compound pH in solution is about 7.2.
 5. The balanced waterpurification composition of claim 1 wherein said acidic component issodium bisulfate, said basic component is sodium bicarbonate, and themolar ratio of sodium bisulfate to sodium bicarbonate is about 0.18,when said buffer compound pH in solution is about
 7. 6. The balancedwater purification composition of claim 1 wherein said acidic componentis present in the composition from about 1.6 to about 21 weight percentand said basic component is present in the composition from about 3 toabout 28 weight percent.
 7. The balanced water purification compositionof claim 6 wherein said acidic component is sodium bisulfate, said basiccomponent is sodium bicarbonate and the weight ratio of sodium bisulfateto sodium bicarbonate is about 0.27.
 8. The balanced water purificationcomposition of claim 1 wherein said acidic component is present in thecomposition from about 6 to about 20.6 weight percent and said basiccomponent is present in the composition from about 4.5 to about 15.4weight percent.
 9. The balanced water purification composition of claim8 wherein said acidic component is sodium bisulfate, said basiccomponent is sodium carbonate and the weight ratio of sodium bisulfateto sodium carbonate is about 1.34.
 10. The balanced water purificationcomposition of claim 1, wherein the weight ratio of said acidiccomponent to said basic component yields a buffer compound having a pHin solution which compensates for an increase in the pH of the waterover time associated with water systems exposed to the atmosphere. 11.The balanced water purification composition of claim 10 wherein saidacidic component is sodium bisulfate, said basic component is sodiumbicarbonate and the weight ratio of sodium bisulfate to sodiumbicarbonate is about 1.5.
 12. The balanced water purificationcomposition of claim 10 wherein said acidic component is sodiumbisulfate, said basic component is sodium carbonate and the weight ratioof sodium bisulfate to sodium carbonate is about 2.27.
 13. The balancedwater purification composition of claim 1, wherein said biocide compoundis Cl₂, Br₂, I₂, alkali metal hypochlorite, alkaline earth metalhypochlorite, chlorinated isocyanurates, PHMB, dichloro-hydantoin,bromohydantoin, or chlorobromohydantoin.
 14. The balanced waterpurification composition of claim 1, wherein said biocide is a halidesalt of ammonium or sodium.
 15. The balanced water purificationcomposition of claim 1, wherein said biocide compound is sodium bromide.16. The balanced water purification composition of claim 1, wherein saidbiocide compound is present in the composition in an amount from about18 to about 35 weight percent.
 17. The balanced water purificationcomposition of claim 1, wherein said oxidizer/clarifier compound is aperoxide, potassium monopersulfate, alkali metal perborate, or alkalimetal persulfate.
 18. The balanced water purification composition ofclaim 1, wherein said oxidizer/clarifier compound is sodium persulfateor potassium persulfate.
 19. The balanced water purification compositionof claim 1, wherein said oxidizer/clarifier compound is present in thecomposition in an amount from about 38 to about 64 weight percent. 20.The balanced water purification of claim 1 wherein saidoxidizer/clarifier compound is present in an amount sufficient tooxidize said biocide compound completely and to oxidize organic matterin the water to be purified.
 21. The balanced water purificationcomposition of claim 1 wherein the molar ratio of saidoxidizer/clarifier compound to said biocide compound is greater than 1.22. The balanced water purification composition of claim 1 werein saidoxidizer/clarifier compound is present in an amount such that when thecomposition is added to water the concentration of saidoxidizer/clarifier compound in the water is from about 2 to about 9parts per million.
 23. The balanced water purification composition ofclaim 22 wherein the concentration of said oxidizer/clarifier in thewater is about 5 ppm.
 24. The balanced water purification composition ofclaim 1 wherein said biocide compound is ammonium chloride and ispresent in the composition from about 18 to about 23 weight percent,said oxidizer/clarifier compound is sodium persulfate and is present inthe composition from about 50 to 64 weight percent and the weight ratioof sodium persulfate to ammonium chloride is about 2.8.
 25. The balancedwater purification composition of claim 1 wherein said biocide compoundis sodium bromide and is present from about 25 to about 35 weightpercent, said oxidizer/clarifier compound is sodium persulfate and ispresent from about 38 to about 52 weight percent, and the weight ratioof sodium persulfate to sodium bromide is about 1.48.
 26. The balancedwater purification composition of claim 1 further comprising analgicide.
 27. The balanced water purification composition of claim 26wherein said algicide is copper sulphate, copper citrate, copper EDTA,copper gluconate, silver nitrate, colloidal silver, silver metal depositon aluminum, polyquats, quats, sodium dimethyldithiocarbamate,2-chloro-4,6-bis(thylamino)-5-triazine, zinc chloride, or zinc oxides.28. The balanced water purification composition of claim 26 wherein saidalgicide is copper sulphate and is present in an amount of from about 1to about 2 weight percent.
 29. The balanced water purificationcomposition of claim 26 wherein said algicide is copper citrate and ispresent in an amount of from about 1.5 to about 2 weight percent. 30.The balanced water purification composition of claim 29 wherein saidcopper citrate is formed in-situ by combining copper sulphate and sodiumcitrate in the composition in a molar ratio of about 1:1.
 31. Thebalanced water purification composition of claim 1 further comprising achelating agent.
 32. The balanced water purification composition ofclaim 31 wherein said chelating agent is EDTA acid, sodium EDTA salts,citric acid, sodium citrate, phosphates, organic phosphonates, ororganic polyphosphonates.
 33. The balanced water purificationcomposition of claim 31 wherein said chelating agent is EDTA acid and ispresent in an amount from about 4.5 to about 14.5 weight percent. 34.The balanced water purification composition of claim 31 wherein saidchelating agent is EDTA disodium salt and is present in an amount offrom about 2.5 to about 18.5 weight percent.
 35. The balanced waterpurification composition of claim 1 further comprising a filtration aid.36. The balanced water purification composition of claim 35 wherein saidfiltration aid is aluminum sulphate and is present in an amount of fromabout 1 up to about 4 weight percent.
 37. The balanced waterpurification composition of claim 1 further comprising a calciumreleasing compound, a scale inhibitor, or a sequestering agent.
 38. Thebalanced water purification composition of claim 1 erein said acidiccomponent is sodium bisulfate and is present in an amount from about 1.6to about 6.1 weight percent, said basic component is sodium bicarbonatepresent in an amount from about 5.9 to about 22.4 weight percent, theweight ratio of sodium bisulfate to sodium bicarbonate is about 0.27,said biocide compound is ammonium chloride and is present in an amountfrom about 18 to about 23 weight percent, said oxidizer/clarifiercompound is sodium persulfate present in an amount from about 50 toabout 64 weight percent, and the weight ratio of sodium persulfate toammonium chloride is about 2.8.
 39. The balanced water purificationcomposition of claim 38 further comprising copper sulphate in an amountfrom about 1 to about 2 weight percent.
 40. The balanced waterpurification composition of claim 1 wherein said acidic component issodium bisulfate and is present in an amount from about 2.7 up to about7.6 weight percent, said basic component is sodium bicarbonate and ispresent in an amount from about 10 to about 28 weight percent, theweight ratio of sodium bisulfate to sodium bicarbonate is about 0.27,said biocide compound is sodium bromide present in amount from about 25to about 35 weight percent, said oxidizer/clarifier compound is sodiumpersulfate present in an amount from about 38 to about 52 weight percentand the weight ratio of sodium persulfate to sodium bromide is about1.48.
 41. The balanced water purification composition of claim 40further comprising copper sulfate present in an amount of from about 1to about 2 weight percent.
 42. The balanced water purificationcomposition of claim 40 further comprising copper citrate from about 1to about 2 weight percent.
 43. The balanced water purificationcomposition of claim 1 further comprising a water soluble film bag forholding the composition.
 44. The balanced water purification compositionof claim 43 wherein said water soluble film bag comprises polyvinylalcohol, a cellulosic polymer, or polyethylene oxide.
 45. A method formaking a balanced water purification composition to be used in beatingwater, which composition does not change the pH of the water to which itis added, the method comprising:a) determimng the pH and temperaturerange of the water to be treated; b) formulating a buffer compoundhaving an acidic component and a buffer component present in a molarratio equivalent to the pH of the water to be treated; c) adding asufficient amount of a biocide compound to inactivate the biologicalcontaminants in the water; and d) adding a sufficient amount of aclarifier/oxidizer compound to oxidize the biocide compound completelyand to oxidize organic matter in the water.
 46. The method of claim 44further comprising adding the composition to a water soluble film bag.47. The method of claim 46 wherein the water soluble film bag comprisespolyvinyl alcohol, a cellulosic fiber, or polyethylene oxide.
 48. Amethod of purifying and clarifying recreational waters comprisinga)formulating a balanced water purification composition according to themethod of claim 45, and b) adding the composition to the recreationalwaters in an amount sufficient to provide clarification and purificationof the water.